Synergistic photocatalytic aerobic oxidation of sulfides and amines on TiO2 under visible-light irradiation
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چکیده
منابع مشابه
Photocatalytic Oxidation of Propylene on Pd-Loaded Anatase TiO2 Nanotubes Under Visible Light Irradiation
TiO2 nanotubes attract much attention because of their high photoelectron-chemical and photocatalytic efficiency. But their large band gap leads to a low absorption of the solar light and limits the practical application. How to obtain TiO2 nanotubes without any dopant and possessing visible light response is a big challenge nowadays. Orthorhombic titanic acid nanotubes (TAN) are a special prec...
متن کاملSynergistic photocatalytic aerobic oxidation of sulfides and amines on TiO2 under visible-light irradiation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c4sc02891k Click here for additional data file.
Selective photocatalytic aerobic oxidation, which can be conducted under ambient conditions, is of great importance towards achieving sustainable chemistry. However, its practical applications are undermined by several challenges, such as low selectivity, sluggish reaction rates, and the requirement of UV light irradiation. Herein, we report a new concept of synergistic photocatalytic oxidation...
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The selective oxidation of sulfides into sulfoxides receives much attention due to industrial and biological applications. However, the realization of this reaction with molecular oxygen at room temperature, which is of importance towards green and sustainable chemistry, remains challenging. Herein, we develop a strategy to achieve the aerobic oxidation of sulfides into sulfoxides by exploring ...
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Photodegradation of methyl orange was investigated using synthesized TiO2:Mg2+/zeolite as the photocatalyst. The photocatalyst was characterized by X-ray, XRF, FT-IR, and SEM. The photocatalytic activities of TiO2:Mg2+/zeolite samples were evaluated in the degradation of methyl orange under visible light irradiation. The appropriate content of Mg in the composite was obtained as 4.711 wt% with ...
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In this paper, 2wt.% Fe doped TiO2 nanopowder was prepared by a combination of sol-gel and mechanical alloying methods. The mechanical alloying of Fe powder with Ti(OH)4 gel produced from the sol-gel method was used to produce Fe doped TiO2 nanopowder. The synthesized samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and diffuse reflectan...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c4sc02891k